Crystal structures of Na1.85Mg1.85In1.15(PO4)3 and Ag1 .69In1.31(PO4)3 with alluaudite-type structure - Université Polytechnique des Hauts-de-France
Article Dans Une Revue Acta crystallographica Section E : Crystallographic communications [2015-...] Année : 2018

Crystal structures of Na1.85Mg1.85In1.15(PO4)3 and Ag1 .69In1.31(PO4)3 with alluaudite-type structure

Résumé

Single crystals of two new phosphates, sodium magnesium indium(III) tris­(orthophosphate) and silver magnesium indium(III) tris­(orthophosphate), were obtained from solid-state reactions. The two phosphates are isotypic and exhibit alluaudite-type structures. They are characterized by a cationic disorder of the Mg and In sites and a partial occupation of the Na and Ag sites, respectively. The structure of both phosphates is made up of chains of edge-sharing [(Mg,In)O6] octa­hedra extending parallel to [10[\overline{1}]]. Adjacent chains are linked by PO4 tetra­hedra to form a three-dimensional framework delimiting two types of channels parallel to [001] in which the monovalent cations are situated. The coordination numbers of the Na+ cations are 6 and 8, and for both Ag+ cations 6. The corresponding coordination spheres are considerably distorted.

Domaines

Chimie

Dates et versions

hal-04318727 , version 1 (01-12-2023)

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Citer

Ahmed Ould Saleck, Abderrazzak Assani, Mohamed Saadi, Cyrille Mercier, Claudine Follet, et al.. Crystal structures of Na1.85Mg1.85In1.15(PO4)3 and Ag1 .69In1.31(PO4)3 with alluaudite-type structure. Acta crystallographica Section E : Crystallographic communications [2015-..], 2018, E74, pp.1358-1361. ⟨10.1107/S2056989018011799⟩. ⟨hal-04318727⟩
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